Application of singular value decomposition analysis to time-dependent powder diffraction data of an in-situ photodimerization reaction

نویسندگان

  • Ahmed F. Mabied
  • Shunsuke Nozawa
  • Manabu Hoshino
  • Ayana Tomita
  • Tokushi Sato
  • Shin-ichi Adachi
چکیده

Singular value decomposition (SVD) analysis has important applications for time-dependent crystallographic data, extracting significant information. Herein, a successful application of SVD analysis of time-resolved powder diffraction data over the course of an in-situ photodimerization reaction of anthracene derivatives is introduced. SVD revealed significant results in the case of 9-methylanthracene and 1-chloroanthracene. The results support the formation of the 9-methylanthracene stable dimer phase and suggest the existence of an excimer state.

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عنوان ژورنال:

دوره 21  شماره 

صفحات  -

تاریخ انتشار 2014